Ivan Ohlídal, Daniel Franta, Martin Šiler, František Vižďa, Miloslav Frumar, Jaroslav Jedelský, Jaroslav Omasta

Comparison of dispersion models in the optical characterization of As–S chalcogenide thin films

Journal of Non-Crystalline Solids 352 (2006) 5633–5641

In this paper, the optical analysis of the As–S thin films prepared under different conditions is performed using three dispersion models for amorphous materials typically employed in practice. The Tauc–Lorentz (TL) model, Urbach–Cody–Lorentz (UCL) model and our model based on the parameterization of the density of electronic states (PDOS model) are namely used to determine the optical parameters of these films. Within the structural model of the As–S films, the existence of the optical constants profiles and overlayers on to the upper boundaries of these films are included. Dispersion and structural models are employed within the analysis based on a combination of variable angle spectroscopic ellipsometry and transmission spectrophotometry in conjunction with multi-sample modification. It is demonstrated that the TL model is not suitable for the optical characterization of the As–S thin films because of the absence of the Urbach tail. Furthermore, it is shown that both the UCL and PDOS models are satisfactory ones for the optical characterization of these films. Moreover, it is also shown that, using the PDOS dispersion model, one can evaluate the material parameters of these As–S films that correspond to the electronic band structure.

Download PDF (284 kB)

This article may also be available to you online

You can also contact one of the authors: ohlidal@physics.muni.cz, franta@physics.muni.cz

Citing Articles

1. Laidani N., Bartali R., Gottardi G., Anderle M., Cheyssac P.,
   Optical absorption parameters of amorphous carbon films from Forouhi–Bloomer and Tauc–Lorentz models: a comparative study,
   Journal of Physics: Condensed Matter 20 (2008) 015216
2. Sancho-Parramon J., Modreanu M., Bosch S., Stchakovsky M.,
   Optical characterization of HfO₂ by spectroscopic ellipsometry: Dispersion models and direct data inversion,
   Thin Solid Films 516 (2008) 7990–7995
3. Chvostová D., Pajasová L., Železný V.,
   Optical properties of PZT thin films by spectroscopic ellipsometry and optical reflectivity,
   Physica Status Solidi C 5 (2008) 1362–1365
4. Santagneli S. H., Messaddeq S. H., Lima Ribeiro S. J., Messaddeq Y.,
   Photoinduced effects in As-S-P glasses,
   Physica Status Solidi B 246 (2009) 1866–1870

Cited Articles

1. Ohlídal I., Franta D., Frumar M., Jedelský J., Omasta J.,
   Influence of composition, exposure and thermal annealing on optical properties of As–S chalcogenide thin films,
   Chalcogenide Letters 1 (2004) 1–10
2. Franta D., Ohlídal I., Frumar M., Jedelský J.,
   Expression of the optical constants of chalcogenide thin films using the new parameterization dispersion model,
   Applied Surface Science 212–213 (2003) 116–121
3. Franta D., Ohlídal I., Frumar M., Jedelský J.,
   Optical characterization of chalcogenide thin films,
   Applied Surface Science 175–176 (2001) 555–561
4. Ohlídal I., Franta D., Frumar M., Jedelský J., Navrátil K.,
   Complete optical analysis of amorphous As–S chalcogenide thin films by the combined spectrophotometric method,
   Journal of Optoelectronics and Advanced Materials 3 (2001) 873–878
5. Ohlídal I., Franta D.,
   Ellipsometry of thin film systems,
   Progress in Optics 41 (2000) 181-282